Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex

Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex

The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the i...

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Bibliographic Details
Main Authors: Nomura, Mitsushiro, Takayama, Chikako, Janairo, Gerardo C., Sugiyama, Toru, Yokoyama, Yasuo, Kajitani, Masatsugu
Format: text
Published: Animo Repository 2003
Subjects:
Phosphine
Cobalt compounds
Phosphorus compounds
Transition metals
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/4470
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Institution: De La Salle University

Internet

https://animorepository.dlsu.edu.ph/faculty_research/4470

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