Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure

Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure

The reactions of a malonate (C(COOMe)2)-bridged complex with Lewis bases give novel sulfur ylide (M−S sulfur ylide) complex due to the cleavage of Co−C bond as determined by X-ray structure analysis. Acetate (CHCOOEt)- and methylene-bridged complexes, on the other hand, reacted with Lewis bases via...

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Bibliographic Details
Main Authors: Takayama, Chikako, Takeuchi, Keiko, Ohkoshi, Shin-ichi, Janairo, Gerardo C., Sugiyama, Toru, Kajitani, Masatsugu, Sugimori, Akira
Format: text
Published: Animo Repository 1999
Subjects:
Ylides—Structure
Sulfur
Complex compounds
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/6735
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Institution: De La Salle University

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https://animorepository.dlsu.edu.ph/faculty_research/6735

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