Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure

Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure

The reactions of a malonate (C(COOMe)2)-bridged complex with Lewis bases give novel sulfur ylide (M−S sulfur ylide) complex due to the cleavage of Co−C bond as determined by X-ray structure analysis. Acetate (CHCOOEt)- and methylene-bridged complexes, on the other hand, reacted with Lewis bases via...

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Main Authors: Takayama, Chikako, Takeuchi, Keiko, Ohkoshi, Shin-ichi, Janairo, Gerardo C., Sugiyama, Toru, Kajitani, Masatsugu, Sugimori, Akira
Format: text
Published: Animo Repository 1999
Subjects:
Ylides—Structure
Sulfur
Complex compounds
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/6735
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Institution: De La Salle University
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spelling oai:animorepository.dlsu.edu.ph:faculty_research-73442022-08-31T02:11:38Z Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure Takayama, Chikako Takeuchi, Keiko Ohkoshi, Shin-ichi Janairo, Gerardo C. Sugiyama, Toru Kajitani, Masatsugu Sugimori, Akira The reactions of a malonate (C(COOMe)2)-bridged complex with Lewis bases give novel sulfur ylide (M−S sulfur ylide) complex due to the cleavage of Co−C bond as determined by X-ray structure analysis. Acetate (CHCOOEt)- and methylene-bridged complexes, on the other hand, reacted with Lewis bases via an SN2 type reaction to give unstable M−S sulfur ylide complexes and stable six-membered-ring complexes. 1999-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/6735 Faculty Research Work Animo Repository Ylides—Structure Sulfur Complex compounds Chemistry
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
topic Ylides—Structure
Sulfur
Complex compounds
Chemistry
spellingShingle Ylides—Structure
Sulfur
Complex compounds
Chemistry
Takayama, Chikako
Takeuchi, Keiko
Ohkoshi, Shin-ichi
Janairo, Gerardo C.
Sugiyama, Toru
Kajitani, Masatsugu
Sugimori, Akira
Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
description The reactions of a malonate (C(COOMe)2)-bridged complex with Lewis bases give novel sulfur ylide (M−S sulfur ylide) complex due to the cleavage of Co−C bond as determined by X-ray structure analysis. Acetate (CHCOOEt)- and methylene-bridged complexes, on the other hand, reacted with Lewis bases via an SN2 type reaction to give unstable M−S sulfur ylide complexes and stable six-membered-ring complexes.
format text
author Takayama, Chikako
Takeuchi, Keiko
Ohkoshi, Shin-ichi
Janairo, Gerardo C.
Sugiyama, Toru
Kajitani, Masatsugu
Sugimori, Akira
author_facet Takayama, Chikako
Takeuchi, Keiko
Ohkoshi, Shin-ichi
Janairo, Gerardo C.
Sugiyama, Toru
Kajitani, Masatsugu
Sugimori, Akira
author_sort Takayama, Chikako
title Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
title_short Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
title_full Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
title_fullStr Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
title_full_unstemmed Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
title_sort reactions of alkylidene-bridged cobaltadithiolene complexes with lewis bases. formation of m−s sulfur ylide structure
publisher Animo Repository
publishDate 1999
url https://animorepository.dlsu.edu.ph/faculty_research/6735
_version_ 1767196551910785024

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