Reactions of alkylidene-bridged cobaltadithiolene complexes with Lewis bases. Formation of M−S sulfur ylide structure
The reactions of a malonate (C(COOMe)2)-bridged complex with Lewis bases give novel sulfur ylide (M−S sulfur ylide) complex due to the cleavage of Co−C bond as determined by X-ray structure analysis. Acetate (CHCOOEt)- and methylene-bridged complexes, on the other hand, reacted with Lewis bases via...
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Main Authors: | Takayama, Chikako, Takeuchi, Keiko, Ohkoshi, Shin-ichi, Janairo, Gerardo C., Sugiyama, Toru, Kajitani, Masatsugu, Sugimori, Akira |
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Format: | text |
Published: |
Animo Repository
1999
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Subjects: | |
Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/6735 |
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Institution: | De La Salle University |
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