Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex

The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the i...

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Main Authors:	Nomura, Mitsushiro, Takayama, Chikako, Janairo, Gerardo C., Sugiyama, Toru, Yokoyama, Yasuo, Kajitani, Masatsugu
Format:	text
Published:	Animo Repository 2003
Subjects:	Phosphine Cobalt compounds Phosphorus compounds Transition metals Chemistry
Online Access:	https://animorepository.dlsu.edu.ph/faculty_research/4470
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Institution:	De La Salle University

id	oai:animorepository.dlsu.edu.ph:faculty_research-5262
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spelling	oai:animorepository.dlsu.edu.ph:faculty_research-52622021-12-15T07:34:47Z Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex Nomura, Mitsushiro Takayama, Chikako Janairo, Gerardo C. Sugiyama, Toru Yokoyama, Yasuo Kajitani, Masatsugu The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex. 2003-01-06T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/4470 info:doi/10.1021/om0207212 Faculty Research Work Animo Repository Phosphine Cobalt compounds Phosphorus compounds Transition metals Chemistry
institution	De La Salle University
building	De La Salle University Library
continent	Asia
country	Philippines Philippines
content_provider	De La Salle University Library
collection	DLSU Institutional Repository
topic	Phosphine Cobalt compounds Phosphorus compounds Transition metals Chemistry
spellingShingle	Phosphine Cobalt compounds Phosphorus compounds Transition metals Chemistry Nomura, Mitsushiro Takayama, Chikako Janairo, Gerardo C. Sugiyama, Toru Yokoyama, Yasuo Kajitani, Masatsugu Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
description	The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex.
format	text
author	Nomura, Mitsushiro Takayama, Chikako Janairo, Gerardo C. Sugiyama, Toru Yokoyama, Yasuo Kajitani, Masatsugu
author_facet	Nomura, Mitsushiro Takayama, Chikako Janairo, Gerardo C. Sugiyama, Toru Yokoyama, Yasuo Kajitani, Masatsugu
author_sort	Nomura, Mitsushiro
title	Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
title_short	Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
title_full	Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
title_fullStr	Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
title_full_unstemmed	Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
title_sort	novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
publisher	Animo Repository
publishDate	2003
url	https://animorepository.dlsu.edu.ph/faculty_research/4470
_version_	1767196097664516096

Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex

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