Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex
The Dimercaptoisotrithione (DMIT) derivative, 4,5-bis(a,a'-dibromo-m-xylyl)- 1,3-dithiole-2-thione, which may act as a precursor for the preparation of cobaltadithiolene complexes, was synthesized. The preparation involved the addition of a base (CsOH-H2) to a solution of 4,5-bis(2'-cyanoe...
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oai:animorepository.dlsu.edu.ph:etd_bachelors-71532021-07-22T15:08:48Z Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex Fong, Mary Dianne Tan, Nikki Andrei The Dimercaptoisotrithione (DMIT) derivative, 4,5-bis(a,a'-dibromo-m-xylyl)- 1,3-dithiole-2-thione, which may act as a precursor for the preparation of cobaltadithiolene complexes, was synthesized. The preparation involved the addition of a base (CsOH-H2) to a solution of 4,5-bis(2'-cyanoethylthio)-1,3-dithiole-2-thione to produce a DMIT salt which was then reacted in situ with a,a'-dibromo-m-xylene. The compound and the by-products were characterized by melting point determination, 1H NMR and IR spectroscopy. 2006-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/etd_bachelors/6509 Bachelor's Theses English Animo Repository Cobalt compounds Chemicals Spectrum analysis Biochemistry |
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Cobalt compounds Chemicals Spectrum analysis Biochemistry |
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Cobalt compounds Chemicals Spectrum analysis Biochemistry Fong, Mary Dianne Tan, Nikki Andrei Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
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The Dimercaptoisotrithione (DMIT) derivative, 4,5-bis(a,a'-dibromo-m-xylyl)- 1,3-dithiole-2-thione, which may act as a precursor for the preparation of cobaltadithiolene complexes, was synthesized.
The preparation involved the addition of a base (CsOH-H2) to a solution of 4,5-bis(2'-cyanoethylthio)-1,3-dithiole-2-thione to produce a DMIT salt which was then reacted in situ with a,a'-dibromo-m-xylene. The compound and the by-products were characterized by melting point determination, 1H NMR and IR spectroscopy. |
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text |
| author |
Fong, Mary Dianne Tan, Nikki Andrei |
| author_facet |
Fong, Mary Dianne Tan, Nikki Andrei |
| author_sort |
Fong, Mary Dianne |
| title |
Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
| title_short |
Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
| title_full |
Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
| title_fullStr |
Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
| title_full_unstemmed |
Synthesis of 4,5-bis (a,a'-Dibromo-m-XYLYL)-1,3-Dithiole-2-Thione: precursor to the preparation of a cobaltadithiolene complex |
| title_sort |
synthesis of 4,5-bis (a,a'-dibromo-m-xylyl)-1,3-dithiole-2-thione: precursor to the preparation of a cobaltadithiolene complex |
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Animo Repository |
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2006 |
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https://animorepository.dlsu.edu.ph/etd_bachelors/6509 |
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