Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage

Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage

The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical ca...

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Bibliographic Details
Main Authors: Alba, Laurenzo De Vera, Hatanaka, Tsubasa, Franco, Francisco C., Jr., Nojiri, Masaki, Noel, Marissa G., Funahashi, Yasuhiro
Format: text
Published: Animo Repository 2021
Subjects:
Glucosinolates
Silver ions
Scission (Chemistry)
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/11273
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Institution: De La Salle University
Description
Summary:The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical calculations with the DFT method indicated relevance to the glucosinolate degradation in biological systems.

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