Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage
The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical ca...
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2021
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oai:animorepository.dlsu.edu.ph:faculty_research-102702023-11-10T01:56:59Z Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage Alba, Laurenzo De Vera Hatanaka, Tsubasa Franco, Francisco C., Jr. Nojiri, Masaki Noel, Marissa G. Funahashi, Yasuhiro The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical calculations with the DFT method indicated relevance to the glucosinolate degradation in biological systems. 2021-01-01T08:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/11273 info:doi/10.1039/d1dt00695a Faculty Research Work Animo Repository Glucosinolates Silver ions Scission (Chemistry) Chemistry |
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De La Salle University |
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De La Salle University Library |
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Asia |
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Philippines Philippines |
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Glucosinolates Silver ions Scission (Chemistry) Chemistry |
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Glucosinolates Silver ions Scission (Chemistry) Chemistry Alba, Laurenzo De Vera Hatanaka, Tsubasa Franco, Francisco C., Jr. Nojiri, Masaki Noel, Marissa G. Funahashi, Yasuhiro Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| description |
The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical calculations with the DFT method indicated relevance to the glucosinolate degradation in biological systems. |
| format |
text |
| author |
Alba, Laurenzo De Vera Hatanaka, Tsubasa Franco, Francisco C., Jr. Nojiri, Masaki Noel, Marissa G. Funahashi, Yasuhiro |
| author_facet |
Alba, Laurenzo De Vera Hatanaka, Tsubasa Franco, Francisco C., Jr. Nojiri, Masaki Noel, Marissa G. Funahashi, Yasuhiro |
| author_sort |
Alba, Laurenzo De Vera |
| title |
Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| title_short |
Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| title_full |
Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| title_fullStr |
Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| title_full_unstemmed |
Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage |
| title_sort |
complex formation of silver(i) ions with a glucosinolate derivative: structural and mechanistic insights into myrosinase-mimicking c-s bond cleavage |
| publisher |
Animo Repository |
| publishDate |
2021 |
| url |
https://animorepository.dlsu.edu.ph/faculty_research/11273 |
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1783960663954030592 |