Complex formation of silver(I) ions with a glucosinolate derivative: Structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage
The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an η2-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the 1H NMR measurements and theoretical ca...
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| Main Authors: | , , , , , |
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| Format: | text |
| Published: |
Animo Repository
2021
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| Subjects: | |
| Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/11273 |
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| Institution: | De La Salle University |