Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatogra...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | text |
| Published: |
Animo Repository
2007
|
| Subjects: | |
| Online Access: | https://animorepository.dlsu.edu.ph/faculty_research/5902 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | De La Salle University |
| Summary: | Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatography. The product was characterized using IR, NMR, UV-Vis and ES-MS. Analysis of the separated product firmly supports the yielding of Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2)2(H2O)2 |
|---|