Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]

Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]

Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatogra...

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Main Authors: Bathan, Victor Francis C., Franco, Francisco C., Guidote, Lourdes P.
Format: text
Published: Animo Repository 2007
Subjects:
Copper compounds
Separation (Technology)
Chemistry
Online Access:https://animorepository.dlsu.edu.ph/faculty_research/5902
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Institution: De La Salle University
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spelling oai:animorepository.dlsu.edu.ph:faculty_research-64912022-05-16T07:38:13Z Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone] Bathan, Victor Francis C. Franco, Francisco C. Guidote, Lourdes P. Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatography. The product was characterized using IR, NMR, UV-Vis and ES-MS. Analysis of the separated product firmly supports the yielding of Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2)2(H2O)2 2007-04-01T07:00:00Z text https://animorepository.dlsu.edu.ph/faculty_research/5902 Faculty Research Work Animo Repository Copper compounds Separation (Technology) Chemistry
institution De La Salle University
building De La Salle University Library
continent Asia
country Philippines
Philippines
content_provider De La Salle University Library
collection DLSU Institutional Repository
topic Copper compounds
Separation (Technology)
Chemistry
spellingShingle Copper compounds
Separation (Technology)
Chemistry
Bathan, Victor Francis C.
Franco, Francisco C.
Guidote, Lourdes P.
Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
description Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatography. The product was characterized using IR, NMR, UV-Vis and ES-MS. Analysis of the separated product firmly supports the yielding of Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2)2(H2O)2
format text
author Bathan, Victor Francis C.
Franco, Francisco C.
Guidote, Lourdes P.
author_facet Bathan, Victor Francis C.
Franco, Francisco C.
Guidote, Lourdes P.
author_sort Bathan, Victor Francis C.
title Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
title_short Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
title_full Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
title_fullStr Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
title_full_unstemmed Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
title_sort synthesis and characterization of a silylene-bridged dicopper complex [cu2(b(3.5- dime)baps)(µ-si(ch3)2(h2o)2], [baps=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]
publisher Animo Repository
publishDate 2007
url https://animorepository.dlsu.edu.ph/faculty_research/5902
_version_ 1767196364727386112

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