Synthesis and characterization of a silylene-bridged dicopper complex [Cu2(B(3.5- dime)BAPS)(µ-Si(CH3)2(H2O)2], [BAPS=bis(3-(2-hydroxybenzylideneamino)phenyl)sulfone]

• Main Authors: Bathan, Victor Francis C., Franco, Francisco C., Guidote, Lourdes P.
• Format: text
• Published: Animo Repository 2007
• Subjects: Copper compounds; Separation (Technology); Chemistry
• Online Access: https://animorepository.dlsu.edu.ph/faculty_research/5902
• Institution: De La Salle University

Cu2(B(3.5- diMe)BAPS)(µ-OME)2 (1) was reacted with (CH3)3SICI (2) to yield a [µ-Si(CH3)2] (3) dicopper complex. The reaction, separation and drying of the product was carried out under dry nitrogen condition. The reaction was monitored using TLC and the separations were done using column chromatogra...