Role of steric strain in the chemistry of phosphiranes
The reaction of transient [MeP-W(CO)5] with norbornene gives the two corresponding exo phosphiranes with W syn or anti to the norbornane bridge. The syn complex is selectively decomplexed by carbon monoxide at 120 °C under 50 bar. Both complexes are easily cleaved by Pd(OAc)2 at room temperature to...
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Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/100844 http://hdl.handle.net/10220/13693 |
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Institution: | Nanyang Technological University |
Language: | English |