Role of steric strain in the chemistry of phosphiranes
The reaction of transient [MeP-W(CO)5] with norbornene gives the two corresponding exo phosphiranes with W syn or anti to the norbornane bridge. The syn complex is selectively decomplexed by carbon monoxide at 120 °C under 50 bar. Both complexes are easily cleaved by Pd(OAc)2 at room temperature to...
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sg-ntu-dr.10356-1008442020-03-07T12:34:50Z Role of steric strain in the chemistry of phosphiranes Ho, Feny Li, Yongxin Mathey, François School of Physical and Mathematical Sciences The reaction of transient [MeP-W(CO)5] with norbornene gives the two corresponding exo phosphiranes with W syn or anti to the norbornane bridge. The syn complex is selectively decomplexed by carbon monoxide at 120 °C under 50 bar. Both complexes are easily cleaved by Pd(OAc)2 at room temperature to give [MeP(OAc)2)]W(CO)5. 2013-09-25T07:23:15Z 2019-12-06T20:29:16Z 2013-09-25T07:23:15Z 2019-12-06T20:29:16Z 2012 2012 Journal Article Ho, F., Li, Y., & Mathey, F. (2012). Role of Steric Strain in the Chemistry of Phosphiranes. Organometallics, 31(23), 8456–8458. https://hdl.handle.net/10356/100844 http://hdl.handle.net/10220/13693 10.1021/om3007807 en Organometallics |
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The reaction of transient [MeP-W(CO)5] with norbornene gives the two corresponding exo phosphiranes with W syn or anti to the norbornane bridge. The syn complex is selectively decomplexed by carbon monoxide at 120 °C under 50 bar. Both complexes are easily cleaved by Pd(OAc)2 at room temperature to give [MeP(OAc)2)]W(CO)5. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Ho, Feny Li, Yongxin Mathey, François |
| format |
Article |
| author |
Ho, Feny Li, Yongxin Mathey, François |
| spellingShingle |
Ho, Feny Li, Yongxin Mathey, François Role of steric strain in the chemistry of phosphiranes |
| author_sort |
Ho, Feny |
| title |
Role of steric strain in the chemistry of phosphiranes |
| title_short |
Role of steric strain in the chemistry of phosphiranes |
| title_full |
Role of steric strain in the chemistry of phosphiranes |
| title_fullStr |
Role of steric strain in the chemistry of phosphiranes |
| title_full_unstemmed |
Role of steric strain in the chemistry of phosphiranes |
| title_sort |
role of steric strain in the chemistry of phosphiranes |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/100844 http://hdl.handle.net/10220/13693 |
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1681035088522903552 |