Synthesis of a Tin(II) 1,3-benzobis(thiophosphinoyl)methanediide complex and its reactions with aluminum compounds

• Main Authors: Yang, Yi-Fan, Foo, Cechao, Ganguly, Rakesh, Li, Yongxin, So, Cheuk-Wai
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2013
• Online Access: https://hdl.handle.net/10356/101097; http://hdl.handle.net/10220/13692
• Institution: Nanyang Technological University

The synthesis of a tin(II) 1,3-benzobis(thiophosphinoyl)methanediide complex and its reactions with aluminum compounds are reported. The reaction of the 1,3-benzodiphosphole disulfide [1,3-C6H4(PhP═S)2CH2] (4) with [Sn{N(SiMe3)2}2] in refluxing toluene afforded the tin(II) 1,3-benzobis(thiophosphino...