Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework

Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework

Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induce...

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Main Authors: Rakesh, Ganguly, Wang, Xiao-Jun, Li, Pei-Zhou, Liu, Lei, Zhang, Quan, Borah, Parijat, Wong, Jinye Daniel, Chan, Xiu Xiang, Li, Yongxin, Zhao, Yanli
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/101388
http://hdl.handle.net/10220/11111
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1013882020-06-01T10:21:29Z Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework Rakesh, Ganguly Wang, Xiao-Jun Li, Pei-Zhou Liu, Lei Zhang, Quan Borah, Parijat Wong, Jinye Daniel Chan, Xiu Xiang Li, Yongxin Zhao, Yanli School of Materials Science & Engineering School of Physical and Mathematical Sciences Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4. 2013-07-10T06:45:38Z 2019-12-06T20:37:44Z 2013-07-10T06:45:38Z 2019-12-06T20:37:44Z 2012 2012 Journal Article Wang, X.-J., Li, P.-Z., Liu, L., Zhang, Q., Borah, P., Wong, J. D., et al. (2012). Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework. Chemical Communications, 48(83), 10268-10288. https://hdl.handle.net/10356/101388 http://hdl.handle.net/10220/11111 10.1039/c2cc34921c en Chemical communications © 2012 The Royal Society of Chemistry.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4.
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Rakesh, Ganguly
Wang, Xiao-Jun
Li, Pei-Zhou
Liu, Lei
Zhang, Quan
Borah, Parijat
Wong, Jinye Daniel
Chan, Xiu Xiang
Li, Yongxin
Zhao, Yanli
format Article
author Rakesh, Ganguly
Wang, Xiao-Jun
Li, Pei-Zhou
Liu, Lei
Zhang, Quan
Borah, Parijat
Wong, Jinye Daniel
Chan, Xiu Xiang
Li, Yongxin
Zhao, Yanli
spellingShingle Rakesh, Ganguly
Wang, Xiao-Jun
Li, Pei-Zhou
Liu, Lei
Zhang, Quan
Borah, Parijat
Wong, Jinye Daniel
Chan, Xiu Xiang
Li, Yongxin
Zhao, Yanli
Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
author_sort Rakesh, Ganguly
title Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
title_short Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
title_full Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
title_fullStr Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
title_full_unstemmed Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework
title_sort significant gas uptake enhancement by post-exchange of zinc(ii) with copper(ii) within a metal–organic framework
publishDate 2013
url https://hdl.handle.net/10356/101388
http://hdl.handle.net/10220/11111
_version_ 1681059296287129600

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