Alkene isomerization-hydroarylation tandem catalysis : indole C2-alkylation with aryl-substituted alkenes leading to 1,1-diarylalkanes

A cobalt-N-heterocyclic carbene catalyst generated from CoBr2, imidazolium salt, and cyclohexylmagnesium bromide was found to promote the imine-directed C2-alkylation of indoles with nonconjugated arylalkenes through a tandem alkene isomerization–hydroarylation process, affording 1,1-diarylalkanes w...

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Main Authors: Yoshikai, Naohiko, Yamakawa, Takeshi
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2014
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在線閱讀:https://hdl.handle.net/10356/102755
http://hdl.handle.net/10220/19125
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機構: Nanyang Technological University
語言: English