Pyrroline synthesis via visible‐light‐promoted hydroimination of unactivated alkenes with N,N′‐dimethylpropylene urea as H‐donor
Synthesis of 3,4-pyrroline derivatives via visible-light-induced hydro/oxyimination of unactivated olefins is reported. In the presence of the photoredox catalyst fac-Ir(ppy)3, the key iminyl radical intermediate can be readily generated from O-acyl oximes, and undergoes intramolecular cyclization a...
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Main Authors: | , , , , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/139419 |
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Institution: | Nanyang Technological University |
Language: | English |