Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate

The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxi...

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Main Authors:	Li, Ying-Zhou, Ganguly, Rakesh, Leong, Weng Kee
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2014
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:	https://hdl.handle.net/10356/103225 http://hdl.handle.net/10220/24383
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-1032252023-02-28T19:43:39Z Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate Li, Ying-Zhou Ganguly, Rakesh Leong, Weng Kee School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxidative addition reaction was trapped as a W(CO)5 adduct. Accepted version 2014-12-09T06:07:15Z 2019-12-06T21:07:52Z 2014-12-09T06:07:15Z 2019-12-06T21:07:52Z 2014 2014 Journal Article Li, Y.-Z., Ganguly, R., & Leong, W. K. (2014). Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate. Organometallics, 33(3), 823-828. https://hdl.handle.net/10356/103225 http://hdl.handle.net/10220/24383 10.1021/om401206d en Organometallics © 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/om401206d]. 6 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Li, Ying-Zhou Ganguly, Rakesh Leong, Weng Kee Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
description	The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxidative addition reaction was trapped as a W(CO)5 adduct.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Li, Ying-Zhou Ganguly, Rakesh Leong, Weng Kee
format	Article
author	Li, Ying-Zhou Ganguly, Rakesh Leong, Weng Kee
author_sort	Li, Ying-Zhou
title	Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
title_short	Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
title_full	Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
title_fullStr	Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
title_full_unstemmed	Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
title_sort	oxidative addition across sb–h and sb–sb bonds by an osmium carbonyl cluster : trapping the intermediate
publishDate	2014
url	https://hdl.handle.net/10356/103225 http://hdl.handle.net/10220/24383
_version_	1759854881872543744

Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate

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