Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxi...
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| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/103225 http://hdl.handle.net/10220/24383 |
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| Institution: | Nanyang Technological University |
| Language: | English |