Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate

• Main Authors: Li, Ying-Zhou, Ganguly, Rakesh, Leong, Weng Kee
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2014
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: https://hdl.handle.net/10356/103225; http://hdl.handle.net/10220/24383
• 機構: Nanyang Technological University

The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxi...