Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)

Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)

Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the p...

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Bibliographic Details
Main Authors: Ho, Feny, Ganguly, Rakesh, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Inorganic chemistry
Online Access:https://hdl.handle.net/10356/103479
http://hdl.handle.net/10220/24536
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Institution: Nanyang Technological University
Language: English
Description
Summary:Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water.

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