Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)

Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)

Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the p...

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Main Authors: Ho, Feny, Ganguly, Rakesh, Mathey, François
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
DRNTU::Science::Chemistry::Inorganic chemistry
Online Access:https://hdl.handle.net/10356/103479
http://hdl.handle.net/10220/24536
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1034792020-03-07T12:34:55Z Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl) Ho, Feny Ganguly, Rakesh Mathey, François School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Inorganic chemistry Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water. 2014-12-26T03:21:22Z 2019-12-06T21:13:34Z 2014-12-26T03:21:22Z 2019-12-06T21:13:34Z 2014 2014 Journal Article Ho, F., Ganguly, R., & Mathey, F. (2014). Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl). European journal of inorganic chemistry, 2014(28), 4726-4729. 1434-1948 https://hdl.handle.net/10356/103479 http://hdl.handle.net/10220/24536 10.1002/ejic.201402662 en European journal of inorganic chemistry © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Inorganic chemistry
spellingShingle DRNTU::Science::Chemistry::Inorganic chemistry
Ho, Feny
Ganguly, Rakesh
Mathey, François
Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
description Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ho, Feny
Ganguly, Rakesh
Mathey, François
format Article
author Ho, Feny
Ganguly, Rakesh
Mathey, François
author_sort Ho, Feny
title Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
title_short Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
title_full Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
title_fullStr Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
title_full_unstemmed Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
title_sort activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [fc-p-w(co)5] (fc = ferrocenyl)
publishDate 2014
url https://hdl.handle.net/10356/103479
http://hdl.handle.net/10220/24536
_version_ 1681042484339146752

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