1-(2′-Anilinyl)prop-2-yn-1-ol rearrangement for oxindole synthesis

1-(2′-Anilinyl)prop-2-yn-1-ol rearrangement for oxindole synthesis

A synthetic method that relies on NIS (N-iodosuccinimide)-mediated cycloisomerization reactions of 1-(2′-anilinyl)prop-2-yn-1-ols to gem-3-(diiodomethyl)indolin-2-ones and 2-(iodomethylene)indolin-3-ones has been developed. The reactions were shown to be chemoselective, with secondary and tertiary a...

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Bibliographic Details
Main Authors: Kothandaraman, Prasath, Koh, Bing Qin, Limpanuparb, Taweetham, Hirao, Hajime, Chan, Philip Wai Hong
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/105286
http://hdl.handle.net/10220/16575
http://dx.doi.org/10.1002/chem.201202606
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/105286
http://hdl.handle.net/10220/16575
http://dx.doi.org/10.1002/chem.201202606

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