Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines

• المؤلفون الرئيسيون: Xu, Haiyan, Yang, Peng, Chuanprasit, Pratanphorn, Hirao, Hajime, Zhou, Steve Jianrong
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2015
• الموضوعات: DRNTU::Science::Chemistry::Physical chemistry::Catalysis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/107036; http://hdl.handle.net/10220/25269; http://dx.doi.org/10.1002/anie.201501018

We report the use of nickel catalysts for the catalytic transfer hydrogenation of hydrazones and other ketimines with formic acid. Strongly donating bisphosphines must be used to support the catalysts. As in enzymatic catalysis, attractive weak interactions may be important for stereochemical contro...