Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals

Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals

A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the su...

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Bibliographic Details
Main Authors: Barik, Chandan Kr, Ganguly, Rakesh, Li, Yongxin, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Science::Chemistry::Inorganic chemistry
Group VIII Metals
[Fe]-Hydrogenase
Online Access:https://hdl.handle.net/10356/136690
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Institution: Nanyang Technological University
Language: English
Description
Summary:A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand.

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