Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals

• Main Authors: Barik, Chandan Kr, Ganguly, Rakesh, Li, Yongxin, Leong, Weng Kee
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2020
• Subjects: Science::Chemistry; Science::Chemistry::Inorganic chemistry; Group VIII Metals; [Fe]-Hydrogenase
• Online Access: https://hdl.handle.net/10356/136690
• Institution: Nanyang Technological University

A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the su...