A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters
C-chirogenic diphosphine-based clusters with 8-membered “chairlike” Cu4Cl4L2 and 12-membered “drumlike” Cu6Cl6L3 (L = diphosphine) frameworks were prepared in one-pot syntheses from chiral diphosphines, which were generated in situ via the double hydrophosphination reaction in excellent enantio- and...
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Main Authors: | , , |
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Other Authors: | |
Format: | Article |
Language: | English |
Published: |
2014
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/103796 http://hdl.handle.net/10220/24558 |
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Institution: | Nanyang Technological University |
Language: | English |