A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters

C-chirogenic diphosphine-based clusters with 8-membered “chairlike” Cu4Cl4L2 and 12-membered “drumlike” Cu6Cl6L3 (L = diphosphine) frameworks were prepared in one-pot syntheses from chiral diphosphines, which were generated in situ via the double hydrophosphination reaction in excellent enantio- and...

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Bibliographic Details
Main Authors: Yang, Xiang-Yuan, Li, Yongxin, Pullarkat, Sumod A.
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/103796
http://hdl.handle.net/10220/24558
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Institution: Nanyang Technological University
Language: English