A one-pot diastereoselective self assembly of C-stereogenic copper(I) diphosphine clusters
C-chirogenic diphosphine-based clusters with 8-membered “chairlike” Cu4Cl4L2 and 12-membered “drumlike” Cu6Cl6L3 (L = diphosphine) frameworks were prepared in one-pot syntheses from chiral diphosphines, which were generated in situ via the double hydrophosphination reaction in excellent enantio- and...
Saved in:
Main Authors: | Yang, Xiang-Yuan, Li, Yongxin, Pullarkat, Sumod A. |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2014
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/103796 http://hdl.handle.net/10220/24558 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
Similar Items
-
Palladium catalyzed asymmetric hydrophosphination of α,β- and α,β,γ,δ-unsaturated malonate esters : efficient control of reactivity, stereo- and regio-selectivity
by: Leung, Pak-Hing, et al.
Published: (2015) -
Mechanistic insights into the PdII-catalyzed chemoselective N-demethylation vs. cyclometalation reactivity pathways in 1-Aryl-N,N-dimethylethanamines
by: Yap, Jeanette See Leng, et al.
Published: (2014) -
Asymmetric catalytic 1,2-dihydrophosphination of secondary 1,2-diphosphines - direct access to free P*- and P*,C*-diphosphines
by: Teo, Ronald Hong Xiang, et al.
Published: (2022) -
A tandem Heck–aza-Michael addition protocol for the one-pot synthesis of isoindolines from unprotected amines
by: Chen, Ke, et al.
Published: (2013) -
Evaluation of palladacycles as a non-rhodium based alternative for the asymmetric conjugate 1,4-addition of arylboronic acids to α,β-unsaturated enones
by: Wong, Jonathan, et al.
Published: (2014)