Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals
A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the su...
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sg-ntu-dr.10356-1366902023-02-28T19:24:51Z Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee School of Physical and Mathematical Sciences Science::Chemistry Science::Chemistry::Inorganic chemistry Group VIII Metals [Fe]-Hydrogenase A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand. MOE (Min. of Education, S’pore) Accepted version 2020-01-10T06:14:18Z 2020-01-10T06:14:18Z 2018 Journal Article Barik, C. K., Ganguly, R., Li, Y., & Leong, W. K. (2018). Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals. Inorganic Chemistry, 57(12), 7113-7120. doi:10.1021/acs.inorgchem.8b00838 0020-1669 https://hdl.handle.net/10356/136690 10.1021/acs.inorgchem.8b00838 29799728 2-s2.0-85048691097 12 57 7113 7120 en Inorganic Chemistry This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b00838 application/pdf |
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Science::Chemistry Science::Chemistry::Inorganic chemistry Group VIII Metals [Fe]-Hydrogenase |
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Science::Chemistry Science::Chemistry::Inorganic chemistry Group VIII Metals [Fe]-Hydrogenase Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| description |
A set of structural mimics of the [Fe]-hydrogenase active site comprising all the group VIII metals, viz., [M(2-NHC(O)C5H4N)(CO)2(2-S-C5H4N)], has been synthesized. They exist as a mixture of isomers in solution, and the relative stability of the isomers depends on the nature of the metal and the substituent at the 6-position of the pyridine ligand. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| format |
Article |
| author |
Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Leong, Weng Kee |
| author_sort |
Barik, Chandan Kr |
| title |
Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| title_short |
Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| title_full |
Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| title_fullStr |
Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| title_full_unstemmed |
Structural mimics of the [Fe]-hydrogenase : a complete set for group VIII metals |
| title_sort |
structural mimics of the [fe]-hydrogenase : a complete set for group viii metals |
| publishDate |
2020 |
| url |
https://hdl.handle.net/10356/136690 |
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1759853767980744704 |