Regioselective copper-catalyzed oxidative coupling of α-alkylated styrenes with tertiary alkyl radicals

Regioselective copper-catalyzed oxidative coupling of α-alkylated styrenes with tertiary alkyl radicals

A radical-mediated oxidative cross-coupling of readily accessible α-alkylated styrenes with 1,3-dicarbonyl compounds utilizing a combination of Cu(OAc)2 and air as a catalytic system is described. Rather than requiring α-halocarbonyl compounds, this efficient approach enables direct installation of...

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Bibliographic Details
Main Authors: Wang, Cong, Liu, Rui-Hua, Tian, Ming-Qing, Hu, Xu-Hong, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Oxidative Coupling
Radical
Online Access:https://hdl.handle.net/10356/138243
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/138243

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