Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-medi...

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Bibliographic Details
Main Authors: Wang, Yuhuang, Wu, Xingxing, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry::Organic chemistry
Nitrobenzyl Bromides
Nitroalkene
Online Access:https://hdl.handle.net/10356/138311
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Institution: Nanyang Technological University
Language: English
Description
Summary:A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-mediated single-electron-transfer processes for efficient reactions and rapid synthesis.

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