Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

• المؤلفون الرئيسيون: Wang, Yuhuang, Wu, Xingxing, Chi, Robin Yonggui
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry::Organic chemistry; Nitrobenzyl Bromides; Nitroalkene
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/138311

A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-medi...