Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-medi...

Full description

Saved in:
Bibliographic Details
Main Authors: Wang, Yuhuang, Wu, Xingxing, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry::Organic chemistry
Nitrobenzyl Bromides
Nitroalkene
Online Access:https://hdl.handle.net/10356/138311
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-138311
record_format dspace
spelling sg-ntu-dr.10356-1383112023-02-28T19:47:41Z Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions Wang, Yuhuang Wu, Xingxing Chi, Robin Yonggui School of Physical and Mathematical Sciences Science::Chemistry::Organic chemistry Nitrobenzyl Bromides Nitroalkene A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-mediated single-electron-transfer processes for efficient reactions and rapid synthesis. NRF (Natl Research Foundation, S’pore) ASTAR (Agency for Sci., Tech. and Research, S’pore) MOE (Min. of Education, S’pore) Accepted version 2020-05-02T05:37:52Z 2020-05-02T05:37:52Z 2017 Journal Article Wang, Y., Wu, X., & Chi, R. Y. (2017). Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions. Chemical communications, 53(87), 11952-11955. doi:10.1039/c7cc07208b 1359-7345 https://hdl.handle.net/10356/138311 10.1039/c7cc07208b 29052683 2-s2.0-85032642034 87 53 11952 11955 en Chemical communications © 2017 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical communications and is made available with permission of The Royal Society of Chemistry. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry::Organic chemistry
Nitrobenzyl Bromides
Nitroalkene
spellingShingle Science::Chemistry::Organic chemistry
Nitrobenzyl Bromides
Nitroalkene
Wang, Yuhuang
Wu, Xingxing
Chi, Robin Yonggui
Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
description A carbene-catalyzed cascade reaction is developed for the synthesis of multi-substituted indane derivatives. The reaction involves two sequential Michael-addition steps, of which the first step is enabled by an NHC-mediated radical process. This work demonstrates the synthetic potentials of NHC-mediated single-electron-transfer processes for efficient reactions and rapid synthesis.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Yuhuang
Wu, Xingxing
Chi, Robin Yonggui
format Article
author Wang, Yuhuang
Wu, Xingxing
Chi, Robin Yonggui
author_sort Wang, Yuhuang
title Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
title_short Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
title_full Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
title_fullStr Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
title_full_unstemmed Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
title_sort synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions
publishDate 2020
url https://hdl.handle.net/10356/138311
_version_ 1759858222677622784

Similar Items