Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins
A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a...
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| مؤلفون آخرون: | |
| التنسيق: | مقال |
| اللغة: | English |
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2020
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| الوصول للمادة أونلاين: | https://hdl.handle.net/10356/139183 |
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| المؤسسة: | Nanyang Technological University |
| اللغة: | English |
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sg-ntu-dr.10356-1391832020-05-18T02:27:54Z Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins Liang, Qiu-Ju Jiang, Bing Xu, Yun-He Loh, Teck-Peng School of Physical and Mathematical Sciences Science::Chemistry Chemical Reactions Organic Compounds A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a satisfactory tolerance of functional groups. 2020-05-18T02:27:39Z 2020-05-18T02:27:39Z 2018 Journal Article Liang, Q.-J., Jiang, B., Xu, Y.-H., & Loh, T.-P. (2018). Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins. The Journal of Organic Chemistry, 83(15), 8265-8271. doi:10.1021/acs.joc.8b00991 0022-3263 https://hdl.handle.net/10356/139183 10.1021/acs.joc.8b00991 29902382 2-s2.0-85048668406 15 83 8265 8271 en The Journal of Organic Chemistry © 2018 American Chemical Society. All rights reserved. |
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Nanyang Technological University |
| building |
NTU Library |
| country |
Singapore |
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DR-NTU |
| language |
English |
| topic |
Science::Chemistry Chemical Reactions Organic Compounds |
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Science::Chemistry Chemical Reactions Organic Compounds Liang, Qiu-Ju Jiang, Bing Xu, Yun-He Loh, Teck-Peng Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| description |
A practical palladium-catalyzed ortho-olefination of O-acetyl cyanohydrins assisted by synergetic directing groups has been developed. Thus, a range of olefinated O-acetyl cyanohydrins were synthesized in moderate to good yields. The reaction occurs efficiently with high regioselectivity and with a satisfactory tolerance of functional groups. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Liang, Qiu-Ju Jiang, Bing Xu, Yun-He Loh, Teck-Peng |
| format |
Article |
| author |
Liang, Qiu-Ju Jiang, Bing Xu, Yun-He Loh, Teck-Peng |
| author_sort |
Liang, Qiu-Ju |
| title |
Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| title_short |
Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| title_full |
Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| title_fullStr |
Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| title_full_unstemmed |
Palladium-catalyzed regioselective olefination of O-acetyl cyanohydrins |
| title_sort |
palladium-catalyzed regioselective olefination of o-acetyl cyanohydrins |
| publishDate |
2020 |
| url |
https://hdl.handle.net/10356/139183 |
| _version_ |
1681059621074108416 |