Synthesis and crystal structures of salen-type Cu(II) and Ni(II) Schiff base complexes : application in [3+2]-cycloaddition and A3-coupling reactions

• Main Authors: Agrahari, Bhumika, Layek, Samaresh, Ganguly, Rakesh, Pathak, Devendra D.
• Other Authors: School of Chemical and Biomedical Engineering
• Format: Article
• Language: English
• Published: 2020
• Subjects: Science::Chemistry; Cu(II); [3+2]-cycloaddition
• Online Access: https://hdl.handle.net/10356/142692
• Institution: Nanyang Technological University

The synthesis of two new salen-type Schiff base complexes of the type [Cu(L)]·0.5H2O, 1, and [Ni(L)], 2, from the reaction of a 6,6′-[(1E,1′E)-(cyclohexane-1,2-diylbis(azanylylidene))bis(methanylylidene)bis(3-(diethylamino)phenol)] salen-type Schiff base ligand (H2L) with Cu(OAc)2·H2O and Ni(OAc)2·4...