Efficient synthesis of malonate functionalized chiral phosphapalladacycles and their catalytic evaluation in asymmetric hydrophosphination of chalcone

Four chiral phosphapalladacycle complexes functionalized with the malonate moiety at the chiral carbon have been synthesized via a consecutive asymmetric hydrophosphination and cyclometallation protocol. High conversions were achieved in the P–H addition reaction, which was itself catalyzed by a pho...

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Bibliographic Details
Main Authors: Li, Xi-Rui, Chen, Yu, Pang, Benjamin Piaoxiang, Tan, Jaeyu, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/144670
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Institution: Nanyang Technological University
Language: English