Group VIII carbamoyl complexes as catalysts for alkyne hydrocarboxylation and electrochemical proton reduction
A series of group VIII carbamoyl complexes, [M(2-NHC(O)C5H4N)(CO)2(2-SC5H4N)] [where M = Fe, Ru and Os], was found to be efficient and regioselective catalysts for the intramolecular hydroxycarboxylation of α,ω-alkynoic acids, yielding exocyclic enol lactones for ring sizes up to 7 atoms, and endocy...
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Main Authors: | Barik, Chandan Kr, Tessensohn, Malcolm Eugene, Webster, Richard David, Leong, Weng Kee |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/144737 |
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Institution: | Nanyang Technological University |
Language: | English |
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