Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines
The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and comput...
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| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101028 http://hdl.handle.net/10220/13695 |
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| Institution: | Nanyang Technological University |
| Language: | English |