Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines

• المؤلفون الرئيسيون: Kumaran, Elumalai, Leong, Weng Kee
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/101028; http://hdl.handle.net/10220/13695
• المؤسسة: Nanyang Technological University

The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and comput...