Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines
The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and comput...
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sg-ntu-dr.10356-1010282023-02-28T20:02:52Z Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines Kumaran, Elumalai Leong, Weng Kee School of Physical and Mathematical Sciences The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies. MOE (Min. of Education, S’pore) Accepted version 2013-09-25T07:37:20Z 2019-12-06T20:32:16Z 2013-09-25T07:37:20Z 2019-12-06T20:32:16Z 2012 2012 Journal Article Kumaran, E., & Leong, W. K. (2012). Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines. Organometallics, 31(3), 1068–1072. https://hdl.handle.net/10356/101028 http://hdl.handle.net/10220/13695 10.1021/om201134j en Organometallics © 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om201134j]. application/pdf |
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The dinuclear Rh(III) species [Cp*RhCl2]2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH2), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Kumaran, Elumalai Leong, Weng Kee |
| format |
Article |
| author |
Kumaran, Elumalai Leong, Weng Kee |
| spellingShingle |
Kumaran, Elumalai Leong, Weng Kee Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| author_sort |
Kumaran, Elumalai |
| title |
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| title_short |
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| title_full |
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| title_fullStr |
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| title_full_unstemmed |
Rhodium(III)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| title_sort |
rhodium(iii)-catalyzed hydroamination of aromatic terminal alkynes with anilines |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/101028 http://hdl.handle.net/10220/13695 |
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