Diastereoselective intramolecular hydride transfer

This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...

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Bibliographic Details
Main Author: Gandamana, Dhika Aditya
Other Authors: Chiba Shunsuke
Format: Thesis-Doctor of Philosophy
Language:English
Published: Nanyang Technological University 2021
Subjects:
Online Access:https://hdl.handle.net/10356/146238
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Institution: Nanyang Technological University
Language: English
Description
Summary:This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-membered chair-like transition state.