Diastereoselective intramolecular hydride transfer
This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...
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| Format: | Thesis-Doctor of Philosophy |
| Language: | English |
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Nanyang Technological University
2021
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| Online Access: | https://hdl.handle.net/10356/146238 |
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| Institution: | Nanyang Technological University |
| Language: | English |
| Summary: | This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to
undergo reduction of transient carbocation, which is generated upon electrophilic activation of
alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via
the 6-membered chair-like transition state. |
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