Diastereoselective intramolecular hydride transfer

• Main Author: Gandamana, Dhika Aditya
• Other Authors: Chiba Shunsuke
• Format: Thesis-Doctor of Philosophy
• Language: English
• Published: Nanyang Technological University 2021
• Subjects: Science::Chemistry::Organic chemistry::Organic synthesis
• Online Access: https://hdl.handle.net/10356/146238
• Institution: Nanyang Technological University

This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...