Diastereoselective intramolecular hydride transfer

This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...

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Main Author: Gandamana, Dhika Aditya
Other Authors: Chiba Shunsuke
Format: Thesis-Doctor of Philosophy
Language:English
Published: Nanyang Technological University 2021
Subjects:
Online Access:https://hdl.handle.net/10356/146238
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1462382023-02-28T23:48:06Z Diastereoselective intramolecular hydride transfer Gandamana, Dhika Aditya Chiba Shunsuke School of Physical and Mathematical Sciences Shunsuke@ntu.edu.sg Science::Chemistry::Organic chemistry::Organic synthesis This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-membered chair-like transition state. Doctor of Philosophy 2021-02-03T05:49:25Z 2021-02-03T05:49:25Z 2020 Thesis-Doctor of Philosophy Gandamana, D. A. (2020). Diastereoselective intramolecular hydride transfer. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/146238 10.32657/10356/146238 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle Science::Chemistry::Organic chemistry::Organic synthesis
Gandamana, Dhika Aditya
Diastereoselective intramolecular hydride transfer
description This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-membered chair-like transition state.
author2 Chiba Shunsuke
author_facet Chiba Shunsuke
Gandamana, Dhika Aditya
format Thesis-Doctor of Philosophy
author Gandamana, Dhika Aditya
author_sort Gandamana, Dhika Aditya
title Diastereoselective intramolecular hydride transfer
title_short Diastereoselective intramolecular hydride transfer
title_full Diastereoselective intramolecular hydride transfer
title_fullStr Diastereoselective intramolecular hydride transfer
title_full_unstemmed Diastereoselective intramolecular hydride transfer
title_sort diastereoselective intramolecular hydride transfer
publisher Nanyang Technological University
publishDate 2021
url https://hdl.handle.net/10356/146238
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