Diastereoselective intramolecular hydride transfer
This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-member...
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Nanyang Technological University
2021
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sg-ntu-dr.10356-1462382023-02-28T23:48:06Z Diastereoselective intramolecular hydride transfer Gandamana, Dhika Aditya Chiba Shunsuke School of Physical and Mathematical Sciences Shunsuke@ntu.edu.sg Science::Chemistry::Organic chemistry::Organic synthesis This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to undergo reduction of transient carbocation, which is generated upon electrophilic activation of alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via the 6-membered chair-like transition state. Doctor of Philosophy 2021-02-03T05:49:25Z 2021-02-03T05:49:25Z 2020 Thesis-Doctor of Philosophy Gandamana, D. A. (2020). Diastereoselective intramolecular hydride transfer. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/146238 10.32657/10356/146238 en This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). application/pdf Nanyang Technological University |
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Nanyang Technological University |
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NTU Library |
| continent |
Asia |
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Singapore Singapore |
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NTU Library |
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English |
| topic |
Science::Chemistry::Organic chemistry::Organic synthesis |
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Science::Chemistry::Organic chemistry::Organic synthesis Gandamana, Dhika Aditya Diastereoselective intramolecular hydride transfer |
| description |
This thesis focuses on the synthetic applications of diastereoselective 1,5-hydride transfer to
undergo reduction of transient carbocation, which is generated upon electrophilic activation of
alkenes or alcohols. Diastereoselective assembly of these stereogenic centers is enabled via
the 6-membered chair-like transition state. |
| author2 |
Chiba Shunsuke |
| author_facet |
Chiba Shunsuke Gandamana, Dhika Aditya |
| format |
Thesis-Doctor of Philosophy |
| author |
Gandamana, Dhika Aditya |
| author_sort |
Gandamana, Dhika Aditya |
| title |
Diastereoselective intramolecular hydride transfer |
| title_short |
Diastereoselective intramolecular hydride transfer |
| title_full |
Diastereoselective intramolecular hydride transfer |
| title_fullStr |
Diastereoselective intramolecular hydride transfer |
| title_full_unstemmed |
Diastereoselective intramolecular hydride transfer |
| title_sort |
diastereoselective intramolecular hydride transfer |
| publisher |
Nanyang Technological University |
| publishDate |
2021 |
| url |
https://hdl.handle.net/10356/146238 |
| _version_ |
1759856063833702400 |