Iridium-promoted deoxyglycoside synthesis : stereoselectivity and mechanistic insight

Herein, we devised a method for stereoselective O-glycosylation using an Ir(I)-catalyst which enables both hydroalkoxylation and nucleophilic substitution of glycals with varying substituents at the C3 position. In this transformation, 2-deoxy-α-O-glycosides were acquired when glycals equipped with...

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Bibliographic Details
Main Authors: Pal, Kumar Bhaskar, Guo, Aoxin, Das, Mrinmoy, Lee, Jiande, Báti, Gábor, Yip, Benjamin Rui Peng, Loh, Teck-Peng, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Online Access:https://hdl.handle.net/10356/147077
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Institution: Nanyang Technological University
Language: English