Enantioselective intermolecular Heck and reductive Heck reactions of aryl triflates, mesylates, and tosylates catalyzed by nickel

Enantioselective intermolecular Heck and reductive Heck reactions of aryl triflates, mesylates, and tosylates catalyzed by nickel

Nickel-catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2-cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.

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Bibliographic Details
Main Authors: Huang, Xiaolei, Teng, Shenghan, Chi, Robin Yonggui, Xu, Wenqiang, Pu, Maoping, Wu, Yun-Dong, Zhou, Steve Jianrong
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science
Aryl Halides
Heck Reaction
Online Access:https://hdl.handle.net/10356/148218
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Institution: Nanyang Technological University
Language: English
Description
Summary:Nickel-catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2-cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.

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