Enantioselective intermolecular Heck and reductive Heck reactions of aryl triflates, mesylates, and tosylates catalyzed by nickel
Nickel-catalyzed intermolecular Heck reaction of cycloalkenes proceeds well with aryl triflates, mesylates and tosylates in excellent enantiomeric ratios. The asymmetric reductive Heck reaction also works with a 2-cyclopentenone ketal, which is equivalent to conjugate arylation of the enone itself.
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Main Authors: | Huang, Xiaolei, Teng, Shenghan, Chi, Robin Yonggui, Xu, Wenqiang, Pu, Maoping, Wu, Yun-Dong, Zhou, Steve Jianrong |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2021
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/148218 |
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Institution: | Nanyang Technological University |
Language: | English |
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