Iron-catalyzed ortho C−H arylation and methylation of pivalophenone N−H imines

Iron‐catalyzed ortho C−H arylation and methylation reactions of pivalophenone N−H imines are reported. The pivaloyl N−H imine proved an excellent directing group for the arylation with diarylzinc reagents in the presence of an iron‐diphosphine catalyst and 2,3‐dichlorobutane at room temperature. A s...

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Bibliographic Details
Main Authors: Xu, Wengang, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Online Access:https://hdl.handle.net/10356/143930
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Institution: Nanyang Technological University
Language: English