Directed C–H alkenylation of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene catalyst

• المؤلفون الرئيسيون: Lee, Pin-Sheng, Xu, Wengang, Yoshikai, Naohiko
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2019
• الموضوعات: C–H Functionalization; C–C Bond Formation; DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/90280; http://hdl.handle.net/10220/48491
• المؤسسة: Nanyang Technological University

We report herein an ortho‐C–H alkenylation reaction of aryl imines with alkenyl phosphates promoted by a cobalt–N‐heterocyclic carbene (NHC) catalytic system. While commercially available bulky NHC ligands exhibited only modest catalytic activity, elaboration of the nitrogen substituents and backbon...