Pivalophenone imine as a benzonitrile surrogate for directed C–H bond functionalization

• المؤلفون الرئيسيون: Xu, Wengang, Yoshikai, Naohiko
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2018
• الموضوعات: C–H Bond Functionalization; Arylation Reactions
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/86808; http://hdl.handle.net/10220/44261
• المؤسسة: Nanyang Technological University

Pivalophenone N–H imine has been found to serve as a prominent substrate for directed C–H alkylation and arylation reactions with alkyl bromides and aryl chlorides, respectively, under cobalt–N-heterocyclic carbene (NHC) catalysis. Unlike the case of the parent pivalophenone imine, the increased ste...